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1.
Sci Rep ; 9(1): 17051, 2019 Nov 19.
Artigo em Inglês | MEDLINE | ID: mdl-31745101

RESUMO

Terrestrial analogues are often investigated to get insights into the geological processes occurring on other planetary bodies. Due to its thickness and petrological similarities, the pyroxenitic layer of the 120m-thick magmatic pile Theo's Flow (Archean Abitibi greenstone belt Ontario, Canada), has always been regarded as the terrestrial analogue for Martian nakhlites. However, its origin and cooling history and, as a consequence those of nakhlites, have always been a matter of vigorous debate. Did this lava flow originate from a single magmatic event similar to those supposed to occur on Mars or do the different units derive from multiple eruptions? We demonstrate, by a combination of geothermometric constraints on augite single crystals and numerical simulations, that Theo's Flow has been formed by multiple magma emplacements that occurred at different times. This discovery supports the idea that the enormous lava flows with similar compositions observed on Mars could be the result of a process where low viscosity lavas are emplaced during multiple eruptions. This has profound implications for understanding the multiscale mechanisms of lava flow emplacement on Earth and other planetary bodies.

2.
Sci Rep ; 9(1): 15200, 2019 Oct 23.
Artigo em Inglês | MEDLINE | ID: mdl-31645618

RESUMO

Emissivity and reflectance spectra have been investigated on two series of silicate glasses, having compositions belonging to alkaline and subalkaline series, covering the most common terrestrial igneous rocks. Glasses were synthesized starting from natural end-members outcropping at Vulcano Island (Aeolian Islands, Italy) and on Snake River Plain (USA). Results show that the shift of the spectra, by taking Christiansen feature (CF) as a reference point, is correlated with SiO2 content, the SCFM factor and/or the degree of polymerization state via the NBO/T and temperature. The more evolved is the composition, the more polymerized the structure, the shorter the wavelength at which CF is observable. CF shift is also dependent on temperature. The shape of the spectra discriminates alkaline character, and it is related to the evolution of Qn structural units. Vulcano alkaline series show larger amount of Q4 and Q3 species even for mafic samples compared to the subalkaline Snake River Plain series. Our results provide new and robust insights for the geochemical characterization of volcanic rocks by remote sensing, with the outlook to infer origin of magmas both on Earth as well as on terrestrial planets or rocky bodies, from emissivity and reflectance spectra.

3.
Materials (Basel) ; 12(11)2019 Jun 02.
Artigo em Inglês | MEDLINE | ID: mdl-31159493

RESUMO

A new technology was tested to improve the cooking efficiency of the raw mixture for Portland clinker production by the use of nano-Ca(OH)2. A decrease in the free lime concentration after the firing of approximately 35% and 55% in the nano-added clinkers burned at 1350 °C and 1450 °C, respectively, with respect to the standard Portland clinkers was observed. Moreover, in the nano-added clinkers, a slight decrease in alite (C3S), of approximately 2-4 wt%, and increase in belite (C2S), of approximately 5-6 wt%, were observed. Despite these variations, the C2S and C3S abundance lies within the ranges for standard Portland clinkers. The results showed that the nano-addition leads to an increase of the raw mixtures' cooking efficiency. The relatively low energy required for the clinker firing could be used to increase the plant productivity and decrease the CO2 emissions during clinker burning. The decrease of the work index of the clinkers produced by the use of the nano-Ca(OH)2 also contributes to the energy saving during clinker grinding. Differences were also found in the pore size distribution among nano-added clinkers and the standard Portland clinker. The smallest porosities with the modal volume lying in the class of 3∙10-6 mm3 were found to increase by the use of nano-Ca(OH)2. However, the pore volumes higher than 2.0∙10-5 mm3 decreased in the nano-added clinkers.

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